chlorinated oxidizer Applications

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Chlorine dioxide for industrial water treatment

by DuPont Chlorine Dioxide     based in North Kingstown,, RHODE ISLAND (USA)

Chlorine dioxide is used as a biocide in many industrial water treatment applications including cooling towers, process water and mill water.  Its selective oxidative properties usually results in lower dosages of ClO2 while also achieving improved microbial performance.

Chlorine dioxide for municipal wastewater treatment industry

by DuPont Chlorine Dioxide     based in North Kingstown,, RHODE ISLAND (USA)

Wastewater Deodorization: The formation of hydrogen sulfide often poses a problem for municipal wastewater treatment.  Chlorine dioxide, a powerful oxidant, can be effectively used to control noxious, irritating, or pungent odors from many operations.  Moreover, its unique selective properties permit more efficient application at a lower dosage and cost than chorine, hypochlorite, permanganate peroxide or ozone.

Chlorine Dioxide for the Oil & Gas Industry

by DuPont Chlorine Dioxide     based in North Kingstown,, RHODE ISLAND (USA)

Chlorine dioxide (ClO2) is well suited for upstream gas production during oil and gas operations, as well as other oil and gas water applications. Chlorine dioxide is highly effective and more sustainable than other oxidizing or non-oxidizing biocide options.

Oxidation Reduction Potential (ORP)/Redox

by Myron L Company     based in Carlsbad, CALIFORNIA (USA)

Oxidation Reduction Potential or Redox is the activity or strength of oxidizers and reducers in relation to their concentration. Oxidizers accept electrons, reducers lose electrons. Examples of oxidizers are: chlorine, hydrogen peroxide, bromine, ozone, and chlorine dioxide. Examples of reducers are sodium sulfite, sodium bisulfate and hydrogen sulfide. Like acidity and alkalinity, the increase of one is at the expense of the other.

Petrochemical

by Babcock & Wilcox MEGTEC     based in De Pere, WISCONSIN (USA)

Durable regenerative thermal oxidizer (RTO) technology is at the core of our systems. MEGTEC designs and engineers system solutions to meet your special requirements, ranging from energy-efficient treatment of dilute volatile organic compound (VOC) flows, such as tank ventilation, to demanding applications utilizing VOC energy for secondary heat recovery; for example, in the form of process streams. This can include pre- and tail gas treatment systems, and could handle hazardous components such as sulphurous or chlorinated hydrocarbons. For special requirements, we can offer FTO (flameless thermal oxidation) and we can design systems operating safely on oxygen contents below 5%.

Industrial wastewater treatment for industries

by MIOX Corporation     based in Albuquerque, NEW MEXICO (USA)

MIOX is the lowest cost supplier of chlorine for disinfection and oxidation of wastewater prior to discharge. Mixed Oxidant Solution (MOS) chemistry is more effective at biofilm control, Biochemical and Chemical oxygen demand removal (BOD/COD), breakpoint chlorination of ammonia and hydrogen sulfide (H2S) removal.

Applications and Air Pollutants Removed in the Petroleum/Petrochemical Industry

by Bionomic Industries Inc.     based in Mahwah, NEW JERSEY (USA)

Scrubbing of Hydrogen sulfide, mercaptans and other organosulfur compounds from sour gas and other sources. Proprietary regenerative scrubbing chemistries for hydrogen sulfide removal with sulfur production. By-product production systems for producing sodium hydrosulfide (Nash) from hydrogen sulfide. Sulfur dioxide scrubbing. Recover catalyst dust from FCC units. HCL storage tank vent scrubbing. Removal of HCL and particulate from thermal oxidizers burning chlorinated plastics. Marine drilling platforms sulfur dioxide thermal oxidizer emissions.  Asphalt plant scrubbers and hydrogen sulfide emissions from holding tanks. Pilot plant scrubber systems for hydrogen sulfide. Removal of halogenated and sulfur bearing gaseous compounds from high temperature thermal oxidizers and drilling platforms waste. Well drilling hydrochloric acid storage tanks.

Secondary disinfection treatment for commercial & institutional

by MIOX Corporation     based in Albuquerque, NEW MEXICO (USA)

Waterborne illness from microbial growth in water distribution systems is a real threat to water safety. MIOX’s patented Mixed Oxidant Solution (MOS) chemistry for secondary disinfection can help eradicate biofilm that can harbor Legionella and other microorganisms without the use of Chlorine Dioxide. MIOX generators improve workplace safety by eliminating the handling and storage of hazardous chemicals while maintaining steady disinfection residuals.

Municipal Wastewater treatment for drinking water

by MIOX Corporation     based in Albuquerque, NEW MEXICO (USA)

As one of the world`s most precious natural resources, the reuse of water is becoming increasingly important. MIOX is both the most cost-effective solution and the preferred technology for disinfection and oxidation of wastewater for reuse or reintroduction into the environment. MIOX`s hypochlorite generators offer a safer, technologically superior solution to wastewater treatment, virtually eliminating many of the negative problems associated with traditional chlorine disinfection. Safer, economical and significantly more effective, MIOX is revolutionizing the process of making water safe again.

Potable water treatment

by Applied Oxidation LLC     based in Chattanooga, TENNESSEE (USA)

As a selective oxidizing agent, chlorine dioxide possesses several chemical advantages when compared to the traditional use of chlorine in wastewater treatment. Chlorine dioxide does not hydrolyze in water, and thus it retains its biocidal activity over a broader range of pH. It is also non reactive with ammonia and most nitrogen-containing compounds, and thus effective at lower dose levels than chlorine. It also eliminates phenols, simple cyanides and sulfides by oxidation. Likewise it is effective at odor control and will oxidize sulfides. Chlorine dioxide is also effective at oxidizing iron and manganese compounds.

Water treatment

by Applied Oxidation LLC     based in Chattanooga, TENNESSEE (USA)

As a selective oxidizing agent, chlorine dioxide possesses several chemical advantages when compared to the traditional use of chlorine in wastewater treatment. Chlorine dioxide does not hydrolyze in water, and thus it retains its biocidal activity over a broader range of pH. It is also non reactive with ammonia and most nitrogen-containing compounds, and thus effective at lower dose levels than chlorine. It also eliminates phenols, simple cyanides and sulfides by oxidation. Likewise it is effective at odor control and will oxidize sulfides. Chlorine dioxide is also effective at oxidizing iron and manganese compounds.

Water treatment for water distribution systems

by Applied Oxidation LLC     based in Chattanooga, TENNESSEE (USA)

As a selective oxidizing agent, chlorine dioxide possesses several chemical advantages when compared to the traditional use of chlorine in wastewater treatment. Chlorine dioxide does not hydrolyze in water, and thus it retains its biocidal activity over a broader range of pH. It is also non reactive with ammonia and most nitrogen-containing compounds, and thus effective at lower dose levels than chlorine. It also eliminates phenols, simple cyanides and sulfides by oxidation. Likewise it is effective at odor control and will oxidize sulfides. Chlorine dioxide is also effective at oxidizing iron and manganese compounds.

Water Disinfection for Municipal Water Treatment

by MIOX Corporation     based in Albuquerque, NEW MEXICO (USA)

As one of the world`s most precious natural resources, the reuse of water is becoming increasingly important. MIOX is both the most cost-effective solution and the preferred technology for disinfection and oxidation of wastewater for reuse or reintroduction into the environment. MIOX`s hypochlorite generators offer a safer, technologically superior solution to wastewater treatment, virtually eliminating many of the negative problems associated with traditional chlorine disinfection. Safer, economical and significantly more effective, MIOX is revolutionizing the process of making water safe again.

Water treatment for cooling towers

by Applied Oxidation LLC     based in Chattanooga, TENNESSEE (USA)

Controlling and preventing the growth of microorganisms in a cooling tower is extremely important and required to keep the system running at optimal levels. The presence of microorganisms will cause the system to breakdown and decreases the efficiency of the heat transfer. Typically oxidizing biocides such as chlorine and bromine have been used to treat cooling water. Unfortunately these chemicals are highly reactive with other chemicals and microbiological species found in the water. Chlorine dioxide however is very non-reactive to other compounds found in the water and retains biocidal efficacy. Likewise it is also a superior chemical for removing the biofilm, which leads to the most predominant problems that all cooling towers face.

Cyanide Treatment with Hydrogen Peroxide

by USP Technologies     based in Atlanta, GEORGIA (US) (USA)

Cyanides are used in a number of chemical synthesis and metallurgical processes (as simple salts or cyanide complexes). As a class, cyanides are highly toxic and must be destroyed or removed from wastewaters prior to discharge. The most common method for treating free or simple cyanide is alkaline chlorination. However, chlorination of cyanide results in highly toxic intermediates (e.g., cyanogen chloride) and, if organic material is present, chlorinated VOC’s. These compounds, together with the residual chlorine, create additional environmental problems. Consequently, there is a growing need for alternative, non-chlorine methods for destroying cyanides. Peroxygen compounds such as hydrogen peroxide, peroxymonosulfuric acid (1), and persulfates (1) are effective alternatives to alkaline chlorination for destroying free and complexed cyanides. The choice of peroxygen system depends on the reaction time available, the desired products (cyanate, or CO2 and NH3), the types of cyanides being treated (free, weak acid dissociable, or inert), and the system economics. Treatment with Hydrogen Peroxide While hydrogen peroxide will oxidize free cyanide, it is common to catalyze the reaction with a transition metal such as soluble copper, vanadium, tungsten or silver in concentrations of 5 to 50 mg/L (2).

Odor Scrubbers Applications with Hydrogen Peroxide

by USP Technologies     based in Atlanta, GEORGIA (US) (USA)

Hydrogen Peroxide as a Replacement for Sodium Hypochlorite Hydrogen peroxide may be used in both mist scrubbers and packed tower scrubbers as a replacement for sodium hypochlorite (bleach). Like bleach, the process involves two concurrent mechanisms: 1) absorption of the odors (H2S) into the alkaline scrubbing solution; and 2) oxidation of the absorbed sulfide in solution. Step 1: H2S + NaOH → NaSH + H2O Step 2: 4H2O2 + H2S → H2SO4 + 4H2O Typical dose ratios are 5 parts H2O2 per part H2S or, when used in place of bleach, one gallon 50% H2O2 for every 10 gallons of 15% sodium hypochlorite (NaOCl). This generally translates into a break-even cost scenario. Sufficient caustic soda (NaOH) is added to maintain a pH of 10.0 - 10.5 in the scrubbing solution. There is also in practice a process which uses H2O2 in series with bleach to scrub composting odors. This process relies on a series of three packed tower scrubbers: the first is a pH neutral water wash (to remove ammonia and amine odors); the second uses a conventional caustic/bleach solution in which the bleach is purposely overdosed (to oxidize the complex organic sulfur odors); and the third uses a caustic/H2O2 solution (to remove the unreacted chlorine vapors carried over from the second stage). H2O2 + HOCl → HCl + H2O + O2 Typical dose ratios are 0.5 parts H2O2 per part hypochlorite (OCl-), with sufficient caustic soda (NaOH) added to maintain a pH of 8.5 in the scrubbing solution.

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