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preventive odor control Applications

  • Headworks Odor and Corrosion Control Using Hydrogen Peroxide

    Hydrogen Peroxide typically controls odors and corrosion at treatment plant headworks by direct oxidation of hydrogen sulfide (H2S) within the wastewater. In the direct oxidation mode, H2O2 is applied to the wastewater 5-30 minutes prior to the point where the odors are being released, generally as the wastewater line enters the plant boundary. The efficiency of hydrogen peroxide treatment depends upon the available reaction time, the level of iron in the wastewater (reaction catalyst), wastewater pH and temperature, and the initial and target levels of H2S odor. Under optimal conditions, effective dose ratios are 1.2 - 1.5 parts H2O2 per part dissolved sulfide, and can be reliably estimated through beaker tests. H2O2 + H2S → S0 + 2H2O Frequently, control of odors through the primary clarifiers is wanted. In such case, the mechanism of control is both direct oxidation of H2S (as it rises from the solids blanket), and prevention of odor generation (by supplying dissolved oxygen). Control is typically achieved with a booster dose of 1-2 mg/L H2O2 added to the clarifier influent. Higher doses or alternate modes of addition may be required in cases where: 1) hydraulic retention times are > 2-3 hours; 2) solids blanket depths are > 1-2 feet; 3) soluble BOD levels are > 200-300 mg/L; or 4) waste activated sludge is co-settled with the primary solids. 2H2O2 → O2 + 2H2O

    By USP Technologies based in Atlanta, GEORGIA (US) (USA).

  • Process Design

    Custom water and wastewater engineering, consulting and process design services to prevent air, land, water and environmental pollution. We rework systems as processes change and troubleshoot where necessary to bring systems into compliance. • High purity and process water • Biological nutrient removal • Solids treatment • Toxicity reduction • Industrial treatment • Advanced oxidation and alternative disinfection • Effluent reclamation and reuse • Land application systems • Natural treatment systems • Hydrogen sulfide and odor control • Decentralized treatment systems • Process optimization / operations assistance • Conceptual and strategic water planning

    By Yates Environmental Services based in Spokane, WASHINGTON (USA).

  • Sulfide Oxidation with Hydrogen Peroxide (H2O2)

    Sulfide Odor Control Sulfide is found throughout the environment as a result of both natural and industrial processes. Most sulfide found in nature was produced biologically (under anaerobic conditions) and occurs as free hydrogen sulfide (H2S) - characterized by its rotten egg odor. We are most likely to encounter biogenic H2S in sour groundwaters, swamps and marshes, natural gas deposits, and sewage collection/treatment systems. Manmade sources of H2S typically occur as a result of natural materials containing sulfur (e.g., coal, gas and oil) being refined into industrial products. For a variety of reasons - aesthetics (odor control), health (toxicity), ecological (oxygen depletion in receiving waters), and economic (corrosion of equipment and infrastructure) - sulfide laden wastewaters must be handled carefully and remediated before they can be released to the environment. Typical discharge limits for sulfide are < 1 mg/L. Sulfide Treatment Alternatives There are dozens of alternatives for treating sulfide laden waters, ranging from simple air stripping (for the low levels present in groundwaters) to elaborate sulfur recovery plants (used to treat several tons per day at refineries and coal burning power plants). There are processes based on biology (using compost filters, scrubbing media, or inhibition/disinfection), chemistry (oxidation, precipitation, absorption, and combination), and physics (adsorption, volatilization, and incineration). Each process occupies a niche which is often defined by the scale and continuity of treatment, whether the sulfide is in solution or is a gas, the concentration of sulfide involved, and the disposition of the sulfide containing medium. However, for reasons relating to convenience and flexibility, chemical oxidation (using hydrogen peroxide) continues to grow in its scope of application. Treatment with Hydrogen Peroxide While other peroxygens such as permonosulfuric (Caro’s) acid, peracetic acid, and persulfates will oxidize sulfide, their use for this application is overkill. Hydrogen peroxide (H2O2) is considerably simpler and more cost-effective. H2O2 may control sulfides in two ways, depending on the application: Prevention - by providing dissolved oxygen which inhibits the septic conditions which lead to biological sulfide formation; and Destruction - by oxidizing sulfide to elemental sulfur or sulfate ion.

    By USP Technologies based in Atlanta, GEORGIA (US) (USA).

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