Browse all Channels
IWA Publishing
  2. Companies
  3. IWA Publishing
  4. Articles
  5. Aniline chlorination by in situ formed Ag–Cl complexes ...

Aniline chlorination by in situ formed Ag–Cl complexes under simulated solar light irradiation

0
- By: , , , ,

Courtesy of IWA Publishing

Ag speciation in a chloride medium was dependent upon the Cl/Ag ratio after releasing into surface water. In this study, the photoreaction of in situ formed Ag–Cl species and their effects on aniline photochlorination were systematically investigated. Our results suggested that formation of chloroaniline was strongly relevant to the Cl/Ag ratio and could be interpreted using the thermodynamically expected speciation of Ag in the presence of Cl−. AgCl was the main species responsible for the photochlorination of aniline. Both photoinduced hole and •OH drove the oxidation of Cl− to radical •Cl, which promoted the chlorination of aniline. Ag0 formation was observed from the surface plasmon resonance absorption during AgCl photoreaction. This study revealed that Ag+ released into Cl−-containing water may result in the formation of chlorinated intermediates of organic compounds under solar light irradiation.

Related articles

  • Inline Magnets Remove Metal from Potassium Chloride

    A UK processor of Potassium Chloride is using two Pneumatic Inline Magnets (PIMS) to capture and remove small tramp ferrous metal. The metal is removed early in the process, as the dry material is ...

  • How to make oxygen sensors have a long life

    It is a question we are asked frequently: How to make oxygen sensors have a long life? There are many things we can do, but also, more importantly, there are many chemicals and gases we ...

  • Types of Marine Sanitation Devices (MSDs)

    When you’re crafting, purchasing, or maintaining your vessel, it can be easy to get caught up in the exciting specifics of boat care: the equipment you use to perform daily tasks, the engines ...

  • Using Nonwoven Face Masks

    Using Nonwoven Face Masks

    A medical mask, also called a sanitary mask, is designed to be worn only by medical professionals while in medical procedures. They are specifically designed to catch bacteria and viruses that are ...

Customer comments

No comments were found for Aniline chlorination by in situ formed Ag–Cl complexes under simulated solar light irradiation. Be the first to comment!