Dehalogenation

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Introduction:

Contaminated soil is screened, processed with a crusher and pug mill, and mixed with reagents. The mixture is heated in a reactor. The dehalogenation process is achieved by either the replacement of the halogen molecules or the decomposition and partial volatilization of the contaminants.

Base-catalyzed Decomposition (BCD)

Base-catalyzed decomposition (BCD) process was developed by EPA's Risk Reduction Engineering Laboratory (RREL), in cooperation with the Naval Facilities Engineering Services Center (NFESC) to remediate soils and sediments contaminated with chlorinated organic compounds, especially PCBs, dioxins, and furans. Contaminated soil is screened, processed with a crusher and pug mill, and mixed with sodium bicarbonate. The mixture is heated to above 330 ° (630 °) in a reactor to partially decompose and volatilize the contaminants. The volatilized contaminants are captured, condensed, and treated separately.

Glycolate/Alkaline Polyethylene Glycol (APEG)

Glycolate is a full-scale technology in which an alkaline polyethylene glycol (APEG) reagent is used. Potassium polyethylene glycol (KPEG) is the most common APEG reagent. Contaminated soils and the reagent are mixed and heated in a treatment vessel. In the APEG process, the reaction causes the polyethylene glycol to replace halogen molecules and render the compound nonhazardous or less toxic. The reagent (APEG) dehalogenates the pollutant to form a glycol ether and/or a hydroxylated compound and an alkali metal salt, which are water-soluble byproducts. Dehalogenation (APEG/KPEG) is generally considered a stand alone technology; however, it can be used in combination with other technologies. Treatment of the wastewater generated by the process may include chemical oxidation, biodegradation, carbon adsorption, or precipitation.

Dehalogenation is normally a short- to medium-term process. The contaminant is partially decomposed rather than being transferred to another medium.

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