John Wiley & Sons, Ltd.

Transformation of graphene oxide by ferrous iron: Environmental implications

- By: , , ,

Courtesy of Courtesy of John Wiley & Sons, Ltd.

Abiotic transformation of graphene oxide (GO) in aquatic environments can markedly affect the fate, transport, and effects of GO. We observed that ferrous iron (Fe(II))—an environmentally abundant, mild reductant—can significantly affect the physicochemical properties of GO (examined by treating aqueous GO suspensions with Fe2+ at room temperature, with doses of 0.032, 0.08, and 0.32 mM Fe2+ per mg/L GO). Microscopy data showed stacking of GO nanosheets upon Fe2+ treatment. Spectroscopy evidence (X‐ray diffraction, Fourier transform infrared transmission, Raman and X‐ray photoelectron spectroscopy) revealed significant changes in GO surface O‐functionalities, in terms of loss of epoxy and carbonyl groups but increase of carboxyl group. The reduction mechanisms were verified by treating model organic molecules (styrene oxide, p‐benzoquinone, and benzoic acid) resembling O‐containing fragments of GO macromolecules with Fe2+. With sedimentation and adsorption experiments (using bisphenol A as a model contaminant), we demonstrated that Fe2+‐reduced GOs still maintained relatively high colloidal stability, while their adsorption affinities were significantly enhanced. Thus, reduction of GO by mild reductants might be of greater environmental concerns than by stronger reducing agents (e.g., N2H4 and S2−), because the latter can result in too significant losses of surface O‐functionalities and colloidal stability of GO. This interesting aspect should be given a consideration in the risk assessment of GO. This article is protected by copyright. All rights reserved

Customer comments

No comments were found for Transformation of graphene oxide by ferrous iron: Environmental implications. Be the first to comment!