A distillation-assisted catalytic oxidation (DACO) process under low temperature (100 °C) and atmospheric pressure was investigated to treat heavily contaminated wastewater from oil refining industry. The DACO experiments were carried out in a distillation batch reactor, using CuO/γ-A12O3 as catalyst. The experimental temperature was kept at 100 °C and H2O2 oxidant was supplied into the reactive system with 200 mL/L. The results demonstrated that more than 92.2% of chemical oxygen demand removal was obtained and the absorbance of the refinery wastewater after treatment was zero, indicating significant decolorization efficiency for the solution. The research of life and stability showed that the catalyst had a good stability. The present study indicates that this DACO approach may have a significant application potential for industrial wastewater treatment.
Keywords: catalytic oxidation, combined process, distillation, wastewater treatment