ASTM D1093 - 11 Standard Test Method for Acidity of Hydrocarbon Liquids and Their Distillation Residues


Source: ASTM International

Some petroleum products are treated with mineral acid as part of the refining procedure. Obviously, any residual mineral acid in a petroleum product is undesirable. The absence of a positive indication in the test for acidity of the distillation residue or aqueous extract of a hydrocarbon liquid is an assurance of the care used in refining the fuel or solvent.

1. Scope

1.1 This test method covers the qualitative determination of the acidity of hydrocarbon liquids and their distillation residues. (WarningMany hydrocarbon liquids are extremely flammable. Harmful if inhaled. Hydrocarbon liquid vapors can cause a flash fire.)

1.2 If desired to determine the basicity of a hydrocarbon liquid, proceed in accordance with 9.2 or 9.3, but substitute 3 drops of phenolphthalein indicator solution for the methyl orange indicator. A pink or red color in the aqueous solution when phenolphthalein is used indicates basicity.

1.3 The results obtained by this test method are qualitative expressions. However, for the preparation of reagents and in the procedure, acceptable SI units are to be regarded as the standard.

1.4 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

2. Referenced Documents (purchase separately)

ASTM Standards
D86 Test Method for Distillation of Petroleum Products at Atmospheric Pressure
D91 Test Method for Precipitation Number of Lubricating Oils
D850 Test Method for Distillation of Industrial Aromatic Hydrocarbons and Related Materials
D1078 Test Method for Distillation Range of Volatile Organic Liquids
D1193 Specification for Reagent Water
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products

Index Terms

distillation residue acidity; distillation residue basicity; hydrocarbon acidity; hydrocarbon basicity; Acidity, alkalinity, pH--petroleum products; Distillation--petroleum products; Distillation residue; Hydrocarbons

ICS Code

ICS Number Code 75.080 (Petroleum products in general)

DOI: 10.1520/D1093-11

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