Nitrogen dioxide plays an important role in photochemical smog-forming reactions and, in sufficient concentrations, is deleterious to health, agriculture, materials, and visibility.
In combustion processes, significant amounts of nitric oxide (NO) may be produced by combination of atmospheric nitrogen and oxygen; at ambient temperatures NO can be converted to NO2 by oxygen and other atmospheric oxidants. Nitrogen dioxide may also be generated from processes involving nitric acid, nitrates, the use of explosives, and welding.
1.1 This test method covers the manual determination of nitrogen dioxide (NO2) in the atmosphere in the range from 4 to 10 000 μg/m3 (0.002 to 5 ppm(v)) when sampling is conducted in fritted-tip bubblers.
1.2 For concentrations of NO2 in excess of 10 mg/m3 (5 ppm(v)), as occur in industrial atmospheres, gas burner stacks, or automotive exhaust, or for samples relatively high in sulfur dioxide content, other methods should be applied. See for example Test Method D1608.
1.3 The maximum sampling period is 60 min at a flow rate of 0.4 L/min.
1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are for information only.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. See also 7.2.2 for other precautions.
2. Referenced Documents (purchase separately)
D1071 Test Methods for Volumetric Measurement of Gaseous Fuel Samples
D1193 Specification for Reagent Water
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D1357 Practice for Planning the Sampling of the Ambient Atmosphere
D1608 Test Method for Oxides of Nitrogen in Gaseous Combustion Products (Phenol-Disulfonic Acid Procedures)
D3195 Practice for Rotameter Calibration
D3609 Practice for Calibration Techniques Using Permeation Tubes
D3631 Test Methods for Measuring Surface Atmospheric Pressure
E1 Specification for ASTM Liquid-in-Glass Thermometers
E128 Test Method for Maximum Pore Diameter and Permeability of Rigid Porous Filters for Laboratory Use
ambient atmospheres; analysis; colorimetric analysis; Griess-Saltzman Reaction; nitrogen dioxide; sampling: Air monitoring; Atmospheric analysis; Griess-Saltzman reaction; Nitrogen dioxide (NO2) content;
ICS Number Code 13.040.20 (Ambient atmospheres)
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