ASTM D3268 - 91(2011) standard test method for separation and collection of particulate and gaseous fluorides in the atmosphere (Sodium bicarbonate-coated glass tube and particulate filter method)
The sodium bicarbonate coated tube filter method provides a means of separating and collecting atmospheric gaseous fluoride and particulate fluoride samples.
Since the samples are collected on the dry tube and filter, the fluoride may be eluted with a small volume of eluant (see Section 10 for specific instructions on fluoride elution). Elution into a small volume and the sensitivity of the analytical methods employed allow the analysis of the collected fluoride to fractional parts of a microgram per cubic metre on samples taken for a 12-h period.
1.1 The sodium bicarbonate-coated glass tube and membrane filter method provides a means for the separation and collection of gaseous atmospheric forms of fluoride reactive with sodium bicarbonate and particulate forms of fluoride which are collected by a filter. The test method is applicable to 12-h sampling periods, collecting 1 to 500 μg of gaseous fluoride at a 15 L/min (0.5 ft3/min) sampling rate or about 0.1 to 50 μg/m3. The length of the sampling period can therefore be adjusted so that the amount of fluoride collected will fall within this range. The actual lower limit of the test method will depend upon the sensitivity of the analytical method employed and the quality of reagents used in tube preparation and analysis. It is recommended that the lower limit of detection should be considered as two times the standard deviation of the monthly arithmetic mean blank value. Any values greater than the blank by less than this amount should be reported as “blank value.”
1.2 The values stated in SI units are to be regarded as standard. The inch-pound units in parentheses may be approximate.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately)
D1193 Specification for Reagent Water
D1356 Terminology Relating to Sampling and Analysis of Atmospheres
D1357 Practice for Planning the Sampling of the Ambient Atmosphere
D3266 Test Method for Automated Separation and Collection of Particulate and Acidic Gaseous Fluoride in the Atmosphere (Double Paper Tape Sampler Method)
D3267 Test Method for Separation and Collection of Particulate and Water-Soluble Gaseous Fluorides in the Atmosphere (Filter and Impinger Method)
D3269 Test Methods for Analysis for Fluoride Content of the Atmosphere and Plant Tissues (Manual Procedures)
D3270 Test Methods for Analysis for Fluoride Content of the Atmosphere and Plant Tissues (Semiautomated Method)
ambient atmospheres; analysis; fluoride; gaseous fluoride; particulate fluoride; sampling: Atmospheric analysis--fluoride isolation/analysis; Fluoride content--atmosphere/plant tissues; Glass tube; Particulate gaseous fluorides--atmospheric; Particulate matter content--atmosphere; Sampling air/atmospheric materials/applications; Separation and collection--atmospheric analysis; Sodium bicarbonate;
ICS Number Code 13.040.20 (Ambient atmospheres)
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