ASTM D6304 - 07e1 standard test method for determination of water in petroleum products, lubricating oils, and additives by coulometric karl fischer titration

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Source: ASTM International

A knowledge of the water content of lubricating oils, additives, and similar products is important in the manufacturing, purchase, sale, or transfer of such petroleum products to help in predicting their quality and performance characteristics.

For lubricating oils, the presence of moisture could lead to premature corrosion and wear, an increase in the debris load resulting in diminished lubrication and premature plugging of filters, an impedance in the effect of additives, and undesirable support of deleterious bacterial growth.

1. Scope

1.1 This test method covers the direct determination of water in the range of 10 to 25 000 mg/kg entrained water in petroleum products and hydrocarbons using automated instrumentation. This test method also covers the indirect analysis of water thermally removed from samples and swept with dry inert gas into the Karl Fischer titration cell. Mercaptan, sulfide (S− or H2S), sulfur, and other compounds are known to interfere with this test method (see Section 5).

1.2 This test method is intended for use with commercially available coulometric Karl Fischer reagents and for the determination of water in additives, lube oils, base oils, automatic transmission fluids, hydrocarbon solvents, and other petroleum products. By proper choice of the sample size, this test method may be used for the determination of water from mg/kg to percent level concentrations.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

2. Referenced Documents (purchase separately)

ASTM Standards
D1193 Specification for Reagent Water
D1298 Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products
D5854 Practice for Mixing and Handling of Liquid Samples of Petroleum and Petroleum Products
E203 Test Method for Water Using Volumetric Karl Fischer Titration

Index Terms

coulometric titration; Karl Fischer titration; water: Additives--petroleum products; Karl Fischer coulometric titrator; Lubricating oils; Petroleum products; Water analysis--petroleum products testing;

ICS Code

ICS Number Code 71.040.50 (Physicochemical methods of analysis); 75.080 (Petroleum products in general); 75.100 (Lubricants, industrial oils and related products)

DOI: 10.1520/D6304-07E01

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