Caldo - Complete Pollution Control Systems
Regulated Emissions to Atmosphere; Waste gases are often hot and, if they contain fume or dust, Caldo hot gas filters can be used to remove these solids before the gases are released to atmosphere. However, such gases often also contain other pollutants; hot gas filtration can be combined with other techniques to ensure that all of the controlled substances stay within regulatory limits.
Typical waste gases can contain the following classes of pollutants:
- particulates, such as dust, fume, heavy metals and condensed salts
- acid gases, such as SOx, HCl and HF
- products of incomplete combustion, VOCs and CO;
- the ingredients for the formation of 'de novo' dioxins and furans.
With one or two minor exceptions all of these can be controlled / removed by equipment based around a hot gas filter.
The emission of particulates is prevented by passing the gas through a ceramic filter.The hot gas filter is at the heart of all the pollution control systems supplied by Caldo. The particulate removal efficiency of ceramic filters greatly exceeds all regulatory requirements.
A major category of regulated pollutants is acid gases as listed above. In the atmosphere these gases dissolve in water to produce the acid rain which is so harmful to the natural environment.
Dry scrubbing is a technique for removing components from a gas by reacting them with a solid and then using a hot gas filter to remove the solid. For acid gas removal there is a choice of reactive solids between sodium bicarbonate and hydrated calcium oxide (Ca(OH)2 – commonly called called lime); sodium bicarbonate works best at lower temperatures whereas lime is substantially cheaper.
Caldo has successfully pioneered the use of lime at a higher temperature, 400 degC, in conjunction with hot gas filtration to remove the reacted solid from the gas stream. Operation at this temperature greatly increases the acid gas removal efficiency, reducing operating costs to a minimum.
Caldo has developed a powder feeder for controlling the addition of lime to the gas stream. This compact unit can be sited in a convenient location and it will blow the the metered amount of lime through a small diameter pipe into the inlet duct to the hot gas filter. Alternatively the sorbent can be gravity fed into the filter inlet.
Also known as afterburning, this is generally the first operation performed on the waste gas. It is done in order to complete the combustion of volatile organic compounds (VOCs) and carbon monoxide (CO) that may remain after the initial burning. It involves heating the gas to 850 degC in the presence on at least 6% of oxygen for a period of at least 2 seconds.
In the past the supplier of the primary combustion stage often also produced the secondary. Increasingly, however, Caldo is being asked to supply complete pollution control systems, including the afterburner. We now supply gas or oil fired afterburners to our own design with a choice of refractory linings.
Dry scrubbing is insufficiently effective for NOx removal and an alternative technique, selective non-catalytic reduction (SNCR), must be used. This involves reacting the NOx with ammonia, NH3, at a temperature of about 850 degC. The products of the reaction are nitrogen, N2, and water, H2O, which are both perfectly safe to emit to atmosphere.
The technical challenge for Caldo was to identify and engineer a system for delivering the NH3 safely and effectively into the process. Ammonia is a toxic chemical, dangerous to ship and store so Caldo sought an alternative. Fortunately a common fertiliser, urea, is soluble in water, decomposes to ammonia when heated and is available as a prilled solid, very safe to handle and ship. Caldo has successfully developed equipment to dissolve the prills in water and spray the solution into the process gas at a controlled pressure to achieve the required control of NOx emissions.
The use of urea in solution as a spray was developed mainly to control the high levels of NOx produced by the combustion of ammunition with its high content of bound nitrogen. However, it is now being increasingly sought for processes with nitrogen in the materials being burned or with very high combustion temperatures.