QROS Limited

Heavy Metals Analysis

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On-site heavy metals analysis is accomplished using a technique called X-ray Fluorescence (XRF). There are a number of XRF instruments available but QROS uses XRF analysers from Oxford Instruments. X-ray Fluorescence (XRF) instruments work by exposing a sample to be measured to a beam of X-rays.  The atoms of the sample absorb some of this X-ray energy and become temporarily excited, emitting secondary X-rays upon returning to their ground states.  Each chemical element emits x-rays at unique energies and by measuring the intensities and energies of the emitted X-rays, an XRF analyser can provide qualitative and quantitative analysis regarding the composition of the material being tested. 

The results obtained are tabulated using QROS in house software to present values in  a ppm format and with sample homogeneity flags and site specific total metals exceedence warnings.

Sample homogeneity is a big issue when analysing samples containing made ground. Metals are usually present in their insoluble carbonate or oxide form  and form clumps, unlike hydrocarbons that are usually more evenly dispersed. XRF analysis detects metals within the top few millimetres of the soil sample surface and relies on good sample preparation to obtain the best results. The QROS sample preparation and analysis protocol takes into account these factors and gives results that are usually very close to laboratory results.

There are certain situations where XRF and the laboratory analysis will not agree that well. The first situation is where soil samples contain a very high proportion of stone. Some l;aboratories crush the stone and this is included in the total result. Other laboratories remove the stone and only analyse the fine material. The QROS XRF method analyses only the fine material and reports the results as uncorrected for stone content.

Moisture content will also cause a variation. Soils containing moisture content will give a lower result compared to the same sample if it has been dried. Soils with a moisture content of 20% will therefore have a higher lab result than the XRF because the lab dries soil samples before analysis for metals. The QROS results are reported as uncorrected for moisture content. If an Mcerts laboratory analysis is used, the results should report moisture content and it is possible to compare data that way.

A final reason for a difference in results is down to the nature of the analysis. XRF will detect all metals in the sample, regardless of the matrix, provided they are at a high enough concentration. Laboratory analysis requires samples to be extracted and the extraction acid does not dissolve all of the soil. Metals can be trapped in the acid insoluble matrix and these will not be detected. Arsenic is commonly bound up in Silica Iron matrixes that are insoluble in the usual acids laboratories use to digest the sample.

Analysis by XRF is however a very rapid technique, typically generating results in 30 seconds. The QROS method takes the average of 3 separate analyses on a sample to obtain a more representative result for the sample. This increases the actual per sample analysis time to approximately 3 minutes, including sample preparation.

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