780 - PVC Regular-Bodied Plumbing Cement MSDS

GHS SAFETY DATA SHEETDate Revised: APR 2012Supersedes: SECTION I - PRODUCT AND COMPANY IDENTIFICATION Low VOC Solvent Cement for PVC Plastic Pipe MANUFACTURER: IPS Corporation17109 South Main Street, Gardena, CA 90248-3127P.O. Box 379, Gardena, CA 90247-0379Tel. 1-310-898-3300EMERGENCY: Transportation: CHEMTEL Tel. 800.255-3924, 813-248-0585 (International) Medical: Tel. 800.451.8346, 760.602.8703 3E Company (International)SECTION 2 - HAZARDS IDENTIFICATIONAcute Toxicity: Category 4 Acute Toxicity: None Known Flammable Liquid Category 2Skin Irritation: Category 3 Chronic Toxicity: None KnownSkin Sensitization: NOEye: GHS LABEL: Signal Word: WHMIS CLASSIFICATION: CLASS B, DIVISION 2OR DangerH225: Highly flammable liquid and vapor P210: Keep away from heat/sparks/open flames/hot surfaces – No smokingH319: Causes serious eye irritation P261: Avoid breathing dust/fume/gas/mist/vapors/sprayH335: May cause respiratory irritation P280: Wear protective gloves/protective clothing/eye protection/face protectionH336: May cause drowsiness or dizziness P337+P313: Get medical advice/attentionEUH019: May form explosive peroxides P403+P233: Store in a well ventilated place. Keep container tightly closedP501: Dispose of contents/container in accordance with local regulationSECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS CAS# EINECS # CONCENTRATIONPre-registration Number % by WeightTetrahydrofuran (THF) 109-99-9 203-726-8 05-2116297729-22-0000 10 - 30Methyl Ethyl Ketone (MEK) 78-93-3 201-159-0 05-2116297728-24-0000 25 - 40Cyclohexanone 108-94-1 203-631-1 05-2116297718-25-0000 20 - 30Acetone 67-64-1 200-662-2 05-2116297713-35-0000 5 - 15All of the constituents of this adhesive product are listed on the TSCA inventory of chemical substances maintained by the US EPA, or are exempt from that listing. * Indicates this chemical is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR372).# indicates that this chemical is found on Proposition 65’s List of chemicals known to the State of California to cause cancer or reproductive toxicity.SECTION 4 - FIRST AID MEASURES Contact with eyes: Flush eyes immediately with plenty of water for 15 minutes and seek medical advice immediately. Skin contact: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water. If irritation develops, seek medical advice. Inhalation: Remove to fresh air. If breathing is stopped, give artificial respiration. If breathing is difficult, give oxygen. Seek medical advice. Ingestion: Rinse mouth with water. Give 1 or 2 glasses of water or milk to dilute. Do not induce vomiting. Seek medical advice immediately.SECTION 5 - FIREFIGHTING MEASURES Suitable Extinguishing Media: Dry chemical powder, carbon dioxide gas, foam, Halon, water fog. HMIS NFPA 0-Minimal Unsuitable Extinguishing Media: Water spray or stream. Health 2 2 1-Slight Exposure Hazards: Inhalation and dermal contact Flammability 3 3 2-Moderate Combustion Products: Oxides of carbon, hydrogen chloride and smoke Reactivity 0 0 3-SeriousPPE B 4-Severe Protection for Firefighters: Self-contained breathing apparatus or full-face positive pressure airline masks.SECTION 6 - ACCIDENTAL RELEASE MEASURES Personal precautions: Keep away from heat, sparks and open flame.Provide sufficient ventilation, use explosion-proof exhaust ventilation equipment or wear suitable respiratory protective equipment.Prevent contact with skin or eyes (see section 8). Environmental Precautions: Prevent product or liquids contaminated with product from entering sewers, drains, soil or open water course. Methods for Cleaning up: Clean up with sand or other inert absorbent material. Transfer to a closable steel vessel. Materials not to be used for clean up: Aluminum or plastic containersSECTION 7 - HANDLING AND STORAGE Handling: Avoid breathing of vapor, avoid contact with eyes, skin and clothing.Keep away from ignition sources, use only electrically grounded handling equipment and ensure adequate ventilation/fume exhaust hoods.Do not eat, drink or smoke while handling. Storage: Store in ventilated room or shade below 44°C (110°F) and away from direct sunlight.Keep away from ignition sources and incompatible materials: caustics, ammonia, inorganic acids, chlorinated compounds, strong oxidizers and isocyanates.Follow all precautionary information on container label, product bulletins and solvent cementing literature.SECTION 8 - PRECAUTIONS TO CONTROL EXPOSURE / PERSONAL PROTECTIONEXPOSURE LIMITS: ACGIH TLV ACGIH STEL OSHA PEL OSHA STEL:Tetrahydrofuran (THF) 50 ppm 100 ppm 200 ppmMethyl Ethyl Ketone (MEK) 200 ppm 300 ppm 200 ppm20 ppm 50 ppm 50 ppmAcetone 500 ppm 750 ppm 1000 ppm Engineering Controls: Use local exhaust as needed. Monitoring: Maintain breathing zone airborne concentrations below exposure limits. Personal Protective Equipment (PPE): Eye Protection: Avoid contact with eyes, wear splash-proof chemical goggles, face shield, safety glasses (spectacles) with brow guards and side shields,etc. as may be appropriate for the exposure. Skin Protection: Prevent contact with the skin as much as possible. Butyl rubber gloves should be used for frequent immersion. Use of solvent-resistant gloves or solvent-resistant barrier cream should provide adequate protection when normal adhesive applicationpractices and procedures are used for making structural bonds. Respiratory Protection: Prevent inhalation of the solvents. Use in a well-ventilated room. Open doors and/or windows to ensure airflow and air changes. Use localexhaust ventilation to remove airborne contaminants from employee breathing zone and to keep contaminants below levels listed above.With normal use, the Exposure Limit Value will not usually be reached. When limits approached, use respiratory protection equipment.Weld-On® 780™ Plumbing Clear Low VOC Cement for PVC Plastic PipePRODUCT NAME:PRODUCT USE:SUPPLIER:GHS CLASSIFICATION:Health Environmental PhysicalWeld-On® 780™ Plumbing Clear Low VOC Cement for PVC Plastic PipeCategory 2BHazard Statements Precautionary StatementsREACH ComponentCyclohexanoneFilename: W-O780 Plumbing Clear LoVoc_6-12.xls Page 1 of 2 6/15/2012 8:24 AM GHS SAFETY DATA SHEETDate Revised: APR 2012Supersedes: Weld-On® 780™ Plumbing Clear Low VOC Cement for PVC Plastic PipeSECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, regular syrupy liquid Odor: Ketone Odor Threshold: 0.88 ppm (Cyclohexanone) pH: Not Applicable Melting/Freezing Point: -108.5°C (-163.3°F) Based on first melting component: THF Boiling Range: 56°C (133°F) to 156°C (313°F) Boiling Point: 56°C (133°F) Based on first boiling component: Acetone Evaporation Rate: > 1.0 (BUAC = 1) Flash Point: -20°C (-4°F) TCC based on Acetone Flammability: Category 2 Specific Gravity: 0.907 @23°C ( 73°F) Flammability Limits: LEL: 1.1% based on Cyclohexanone Solubility: Solvent portion soluble in water. Resin portion separates out. UEL: 12.8% based on Acetone Partition Coefficient n-octanol/water: Not Available Vapor Pressure: 190 mm Hg @ 20°C (68°F) Acetone Auto-ignition Temperature: 321°C (610°F) based on THF Vapor Density: >2.0 (Air = 1) Decomposition Temperature: Not Applicable Other Data: Viscosity: Regular bodied VOC Content: When applied as directed, per SCAQMD Rule 1168, Test Method 316A,VOC content is: < 510 g/l.SECTION 10 - STABILITY AND REACTIVITY Stability: Stable Hazardous decomposition products: None in normal use. When forced to burn, this product gives off oxides of carbon, hydrogen chloride and smoke. Conditions to avoid: Keep away from heat, sparks, open flame and other ignition sources. Incompatible Materials: Oxidizers, strong acids and bases, amines, ammonia SECTION 11 - TOXICOLOGICAL INFORMATIONLikely Routes of Exposure: Inhalation, Eye and Skin ContactAcute symptoms and effects: Inhalation: Severe overexposure may result in nausea, dizziness, headache. Can cause drowsiness, irritation of eyes and nasal passages. Eye Contact: Vapors slightly uncomfortable. Overexposure may result in severe eye injury with corneal or conjunctival inflammation on contact with the liquid. Skin Contact: Liquid contact may remove natural skin oils resulting in skin irritation. Dermatitis may occur with prolonged contact. Ingestion: May cause nausea, vomiting, diarrhea and mental sluggishness.Chronic (long-term) effects: None known to humansToxicity: LD50 LC50 Tetrahydrofuran (THF) Oral: 2842 mg/kg (rat) Inhalation 3 hrs. 21,000 mg/m3 (rat) Methyl Ethyl Ketone (MEK) Oral: 2737 mg/kg (rat), Dermal: 6480 mg/kg (rabbit) Inhalation 8 hrs. 23,500 mg/m3 (rat) Cyclohexanone Oral: 1535 mg/kg (rat), Dermal: 948 mg/kg (rabbit) Inhalation 4 hrs. 8,000 PPM (rat) Acetone Oral: 5800 mg/kg (rat) Inhalation 50,100 mg/m3 (rat)SECTION 12 - ECOLOGICAL INFORMATION Ecotoxicity: None Known Mobility: In normal use, emission of volatile organic compounds (VOC's) to the air takes place, typically at a rate of < 510 g/l. Degradability: Biodegradable Bioaccumulation: Minimal to none.SECTION 13 - WASTE DISPOSAL CONSIDERATIONSFollow local and national regulations. Consult disposal expert. SECTION 14 - TRANSPORT INFORMATION Proper Shipping Name: Adhesives Hazard Class: 3 Secondary Risk: None DOT Limited Quantity: Up to 5L per inner packaging, 30 kg gross weight per package. Identification Number: UN 1133 Consumer Commodity: Depending on packaging, these quantities may qualify under DOT as "ORM-D" . Packing Group: PG II Label Required: Class 3 Flammable Liquid Marine Pollutant: NO TDG CLASS: FLAMMABLE LIQUID 3SHIPPING NAME: ADHESIVESUN NUMBER/PACKING GROUP: UN 1133, PG IISECTION 15 - REGULATORY INFORMATION Precautionary Label Information: Highly Flammable, Irritant Ingredient Listings: USA TSCA, Europe EINECS, Canada DSL, Australia Symbols: F, Xi AICS, Korea ECL/TCCL, Japan MITI (ENCS) Risk Phrases: R11: Highly flammable. R66: Repeated exposure may cause skin dryness or crackingR36/37: Irritating to eyes and respiratory system. R67: Vapors may cause drowsiness and dizziness Safety Phrases: S2: Keep out of the reach of children S25: Avoid contact with eyes.S9: Keep container in a well-ventilated place. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S16: Keep away from sources of ignition - No smoking. S33: Take precautionary measures against static discharges.SECTION 16 - OTHER INFORMATION Specification Information: Department issuing data sheet: IPS, Safety Health & Environmental Affairs All ingredients are compliant with the requirements of the European E-mail address: Directive on RoHS (Restriction of Hazardous Substances). Training necessary: Yes, training in practices and procedures contained in product literature. Reissue date / reason for reissue: 6/15/2012 / Updated GHS Standard Format Intended Use of Product: Solvent Cement for PVC Plastic PipeThis product is intended for use by skilled individuals at their own risk. The information contained herein is based on data considered accurate based on current state ofknowledge and experience. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Reproductive Effects Teratogenicity Mutagenicity Embryotoxicity Sensitization to ProductEXCEPTION for Ground ShippingTDG INFORMATIONSynergistic ProductsNot Established Not Established Not Established Not Established Not Established Not EstablishedFilename: W-O780 Plumbing Clear LoVoc_6-12.xls Page 2 of 2 6/15/2012 8:24 AM