Drain & Trap Deodorizer MSDS Brochure

Page 1 of 3 Material Safety Data Sheet Conforms with OSHA form OMB No. 1218-0072 Roebic Drain & Trap Deodorizer, 4 ½ pounds Roebic Laboratories, Inc. Emergency Telephone Numbers- 25 Connair Road, PO Box 927 ROEBIC (203) 795-1283 Orange, CT 06477 CHEMTREC (800) 424-9300 Date: 11/3/98 Reviewed 06/25/08 Preparer: Dave Lawler SECTION I - INGREDIENTS Product Name/Number Sodium Percarbonate Chemical Name PCS; Sodium Percarbonate; Sodium Carbonate Peroxyhydrate DOT Shipping Name (49 CFR 172.101) Non-regulated* DOT ID Number Non-regulated DOT Hazard Class: Non-regulated *per 49CFR 172.102 special provision 27: Sodium Carbonate Peroxyhydrate is considered non-hazardous OSHA status: This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200 HEALTH (Blue) FLAMMABILITY (Red) REACTIVITY (Yellow) NFPA: No data NFPA: No data NFPA: No data HMIS: 1 HMIS: 1 HMIS: 1 HMIS: PP = F CAS Number 15630-89-4 Generic Description Inorganic peroxygen compound Emergency Overview • A white granular solid that is an irritant to the eyes, skin and respiratory tract. • Not flammable, but damp material decomposes exothermically and may cause combustion of organic material. • Contamination may cause decomposition. SECTION II – COMPOSITION/INFORMATION ON INGREDIENTS COMPONENTS FORMULA CAS # PERCENTSodium Carbonate Peroxyhydrate 2Na2CO3.3H202 15630-89-4 85% Sodium Carbonate Na2CO3 497-19-8 15% SECTION III – HEALTH HAZARD DATA Occupational Exposure Limits: ACGIH – 10mg/m3 8hr TWA for particulate not otherwise classified OSHA – 15mg/m3 8 hr TWA PEL for particulate not otherwise classified Effects of Overexposure: EYES: causes damage to eyes, effects may be delayed SKIN: slightly irritating to the skin INGESTION: harmful if swallowed INHALATION: inhalation of dust may cause irritation to mucous membranes and the respiratory tract. Page 2 of 3 Chronic: Not listed as a carcinogen by ACGIH, IARC, NTP, OSHA Toxicological Information: Acute: Ingestion: LD50 1034 mg/kg – rat-sexes combined Inhalation: Excessive exposure may result in irritation to the mucous membrane and respiratory tract. Skin Contact:: LD50 >2000 mg/kg – dermal, rabbit Eye Contact: Causes damage to eyes, effects may be delayed Chronic: Carcinogenicity: Not recognized as a carcinogen by ACGIH, IARC, NTP, OSHA Mutagenicity: Contains the peroxygen group which in-vitro was shown to be mutagenic without metabolic activation, and generally not mutagenic with metabolic activation. In vivo, no effect has been observed after oral administration. Emergency First aid Procedures: Eyes: Immediately flush eyes with copious amounts of water. Get medical attention. Skin: Brush off. Remove contaminated clothing. Wash with soap and water. Ingestion: Drink large quantities of water. Do not induce vomiting. Get medical attention. Inhalation: Remove to fresh air. Get medical attention if needed. SECTION IV – FIRE AND EXPLOSION HAZARD DATA Flash Point Non-flammable Explosive Limits in Air, % N/A Auto Ignition Temperature N/A Extinguish Media Use water only Special Fire Fighting Procedure Personnel should wear normal protective equipment (full bunker gear) and positive-pressure, self-contained breathing apparatus. If safe to do so, remove unaffected product to a safe area. Unusual Fire Hazard Damp material may decompose exothermically and ignite combustibles. Storage vessels involved in a fire may vent gas or rupture due to internal pressure. Oxygen release due to exothermic decomposition may support combustion. SECTION V – PHYSICAL DATA Appearance/Odor white granular solid, no odor Solubility in H2O 140 g/L @ 75°F Bulk Density 1.0-1.2 g/cc Melting Point N/A can decompose above 55°C Chemical Stability Stable Conditions to Avoid Heat or contamination may cause decomposition. Contact with aqueous or moist conditions with acids or reducing agents can lead to the spontaneous release of oxygen. Incompatible Materials Avoid contacts with acids, alkalis, and reducing agents. Avoid contact with decomposition catalysts, such as the majority of metals and their salts. Avoid contact with combustible and flammable materials. Hazardous Decomposition Products Decomposition produces heat and oxygen Hazardous Polymerization Will not occur Conditions to Avoid no data SECTION VII – SPILL, LEAK & DISPOSAL PROCEDURES For Spill Shovel or sweep product in plastic bags or vented containers for disposal. Do not return spilled or contaminated material to inventory. Wash area down with water. Prevent runoff from entering storm sewers and ditches. Waste Disposal Method Dispose of in approved waste facility operated by an authorized contractor and in compliance with federal, state and local regulations. Page 3 of 3 Ecological Information General: Degradation: Decomposes readily to sodium carbonate and hydrogen peroxide. The latter quickly decomposes to water and oxygen. Aquatic Toxicity: Acute Fish: (Pimephales promelas) LC50(96h) = 70.7 mg/L Acute Daphnia: (Daphnia pulex) LC50(48h) = 4.9 mg/L SECTION VIII – SPECIAL PROTECTION Respiratory Protection Wear NIOSH approved respirator for toxic dust with TLV >0.05 mg/m3 when exposed to irritating or excessive quantities of the dust. Engineering Controls Provide ventilation in work areas to keep dust below the following applicable limits: ACGIH – 10 mg/m3 8 hr TWA for particulate not otherwise classified OSHA – 15 mg/m3 8 hr TWA PEL for particulate not otherwise classified Protective Gloves PVC or Rubber Gloves; suitable coveralls Eye Protection Safety goggles SECTION IX – SPECIAL PRECAUTIONS Precautions to be taken in Handling & Storage Store bags in cool, dry, ventilated area. Store separately from organic and reducing materials. Avoid contamination, which may lead to decomposition. Provide eye wash stations in areas where materials are handled. Other Precautions No data. SECTION X – OTHER REGULATORY INFORMATION TSCA Inventory List Yes CERCLA Hazardous Substance No Reportable Quantity None SARA, Title III Section 302 Extremely Hazardous Substance No Threshold Planning Quantity None Section 311 Hazardous Chemical No Section 313 Toxic Chemical No SECTION I - INGREDIENTS Emergency Overview SECTION II – COMPOSITION/INFORMATION ON INGREDIENTS SECTION IV – FIRE AND EXPLOSION HAZARD DATA Explosive Limits in Air, % N/A Auto Ignition Temperature N/A SECTION V – PHYSICAL DATA SECTION VII – SPILL, LEAK & DISPOSAL PROCEDURES SECTION VIII – SPECIAL PROTECTION SECTION IX – SPECIAL PRECAUTIONS SECTION X – OTHER REGULATORY INFORMATION