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Sealant 5590 Brochure
SAFETY DATA SHEET Based on Directive 2001/58/EC et seq.of the Commission of the European Communities companpla 1.1 Identification of the substance or preparation: Paste 5590 1.2 Use of the substance or the preparation: Sealant 1.3 Company/undertaking identification: 1.4 Telephone number for emergency: Hazardous ingredients CAS-NO. EINECS-NO ELINCS-NO Conc. in% Hazard symbol Risk (R-phrases) butane-2-on-O,O',O''- (vinylsilylidyn)trioxim (*) 2224-33-1 218-747-8 0.1 – 1.0 Xi 38-41-43 (1) oximo silane 1200 37859-57-7 423-580-0- 1.0 – 5.0 Xn 48/22-53 (1 butane-2-on-O,O',O''- (methylsilylidyn)trioxim (*) 22984-54-9 245-366-4 1.0 – 5.0 Xi 36/38-43 (1) (1) For R-phrases in full : see heading 16 - No hazard classification according to Directive 67/548/EEC and 1999/45/EC * Butane-2-on-O,O',O''-(vinylsilylidyn)trioxim and butane-2-on-O,O',O''- (methylsilylidyn)trioxim react with water (moisture): release of 2-butanone oxime (EINECS-nr: 202-496-6; conc <1% - Xn R:21-40-41-43) SEALANT 55901. Identification of the substance/preparation and of the company/undertaking 2. Composition/information on ingredients3. Hazards identification jimmie.bjorkmanMaskinskriven textjimmie.bjorkmanMaskinskriven text jimmie.bjorkmanMaskinskriven textjimmie.bjorkmanMaskinskriven textjimmie.bjorkmanMaskinskriven textSealEcoBox 514, SE-331 25 Värnamo, SwedenPhone: +46 (0)370 510 100Fax: +46 (0)370 510 101E-Mail: info@sealeco.com ,Internet: www.sealeco.comjimmie.bjorkmanMaskinskriven textjimmie.bjorkmanMaskinskriven textjimmie.bjorkmanMaskinskriven textjimmie.bjorkmanMaskinskriven text+46 (0)370 510 100jimmie.bjorkmanMaskinskriven text 4.1 Eye contact: - Rinse immediately with plenty of water - Seek medical advice 4.2 Skin contact: - Wash immediately with lots of water - If irritation persists: seek medical advice 4.3 After inhalation: - Remove the victim into fresh air - Seek medical advice 4.4 After ingestion: - Never give water to an unconscious person - Do not induce vomiting - Seek medical advice 5.1 Suitable extinguishing media: - Water spray - Polyvalent foam - ABC powder - Carbon dioxide 5.2 Unsuitable extinguishing media: - None 5.3 Special exposure hazards: - Not easily combustible - On burning: release of e.g. carbon monoxide and carbon dioxide 5.4 Instructions: - No specific firefighting instructions required 5.5 Special protective equipment for firefighters: - Heat/fire exposure: compressed air/oxygen apparatus 6.1 Personal protection/precautions: See heading 8.1/8.3/10.3 6.2 Environmental precautions: - Use appropriate containment to avoid environmental contamination 6.3 Methods of cleaning up: - Remove the product by mechanical means - Clean contaminated surfaces with a soap solution - Wash clothing and equipment after handling 7.1 Handling: - Observe normal hygiene standards - Clean contaminated clothing 7.2 Storage: - Keep container tightly closed - Store in a dry area SEALANT 5590 4. First aid measures 5. Fire-fighting measures 6. Accidental release measures 7. Handling and storage - Keep away from: heat sources, oxidizing agents Storage temperature : Room temperature Quantity limit : N.D. Storage life : 365 days Materials for packaging : - suitable : plastic 7.3 Specific uses: - See information supplied by the manufacturer 8.1 Exposure limit values: TLV-TWA : not listed TLV-STEL : not listed TLV-Ceiling : not listed OES-LTEL : not listed OES-STEL : not listed MEL-LTEL : not listed MEL-STEL : not listed MAK : not listed TRK : not listed MAC-TGG 8 h : not listed MAC-TGG 15 min. : not listed MAC-Ceiling : not listed VME-8 h : not listed VLE-15 min. : not listed GWBB-8 h : not listed GWK-15 min. : not listed Momentary value : not listed EC : not listed EC-STEL : not listed 8.2 Exposure controls: 8.2.1 Occupational exposure controls: - Work under local exhaust/ventilation 8.2.2 Environmental exposure controls: see heading 13 8.3 Personal protection: 8.3.1 respiratory protection: - Respiratory protection not required in normal conditions 8.3.2 hand protection: - Gloves 8.3.3 eye protection: - Safety glasses 8.3.4 skin protection: - Protective clothing SEALANT 55908. Exposure controls/Personal protection 9.1 General information: Appearance (at 20°C) : Paste Odour : Characteristic Colour : Variable in colour 9.2 Important health, safety and environmental information: pH value : N.D. Boiling point/boiling range : N.A. °C Flashpoint : > 100 °C Explosion limits : N.D. vol% ( °C) Vapour pressure (at 20°C) : N.D. hPa Vapour pressure (at 50°C) : N.D. hPa Relative density (at 20°C) : N.D. Water solubility : Insoluble Soluble in : N.D. Relative vapour density : N.D. Viscosity : N.D. Pa.s Partition coefficient n-octanol/water : N.D. Evaporation rate ratio to butyl acetate : N.D. ratio to ether : N.D. 9.3 Other information: Melting point/melting range : N.A. °C Auto-ignition point : N.D. °C Saturation concentration : N.D. g/m3 10.1 Conditions to avoid/reactivity: - Stable under normal conditions 10.2 Materials to avoid: - Heat sources, oxidizing agents 10.3 Hazardous decomposition products: - On burning: release of e.g. carbon monoxide and carbon dioxide SEALANT 55909. Physical and chemical properties10. Stability and reactivity 11.1 Acute toxicity: LD50 oral rat : N.D. mg/kg LD50 dermal rabbit : N.D. mg/kg LD50 dermal rabbit : N.D. mg/kg LC50 inhalation rat : N.D. mg/l/4 h LC50 inhalation rat : N.D. ppm/4 h 11.2 Chronic toxicity: EC carc. cat. : not listed EC muta. cat. : not listed EC repr. cat. : not listed Carcinogenicity (TLV) : not listed Carcinogenicity (MAC) : not listed Carcinogenicity (VME) : not listed Carcinogenicity (GWBB) : not listed Carcinogenicity (MAK) : not listed Mutagenicity (MAK) : not listed Teratogenicity (MAK) : not listed IARC classification : not listed 11.3 Routes of exposure : ingestion, inhalation, eye and skin 11.4 Acute effects/symptoms: AFTER SKIN CONTACT: - Slight irritation AFTER EYE CONTACT: - Slight irritation 11.5 Chronic effects: - None known SEALANT 559011. Toxicological information 12.1 Ecotoxicity: - No data available 12.2 Mobility: - Volatile organic compounds (VOC): 3 % - Insoluble in water For other physicochemical properties see section 9 12.3 Persistence and degradability: - biodegradation BOD5 : N.D. % ThOD - water : No data available - soil : T ½: N.D. days 12.4 Bioaccumulative potential: - log Pow : N.D. - BCF : N.D. 12.5 Other adverse effects: - WGK : 1 (classification based on the components in compliance with Verwaltungsvorschrift wassergefährdender Stoffe (VwVwS) of 17 May 1999) - Effect on the ozone layer : Not dangerous for the ozone layer (1999/45/EC) - Greenhouse effect : no data available - Effect on waste water purification : no data available 13.1 Provisions relating to waste: - Waste material code (75/442/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001): 08 04 10 (waste adhesives and sealants other than those mentioned in 08 04 09) 13.2 Disposal methods: - Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber 13.3 Packaging: - Waste material code packaging (75/442/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001): 15 01 02 (plastic packaging) SEALANT 559012. Ecological information 13. Waste disposal considerations 14.1 Classification of the substance in compliance with UN Recommendations UN-number : - CLASS : NOT SUBJECT SUB RISKS : PACKING : PROPER SHIPPING NAME : 14.2 ADR (transport by road) CLASS : NOT SUBJECT PACKING : DANGER LABEL TANKS : DANGER LABEL PACKAGES : 14.3 RID (transport by rail) CLASS : NOT SUBJECT PACKING : DANGER LABEL TANKS : DANGER LABEL PACKAGES : 14.4 ADNR (transport by inland waterways) CLASS : NOT SUBJECT PACKING : DANGER LABEL TANKS : DANGER LABEL PACKAGES : 14.5 IMDG (maritime transport) CLASS : NOT SUBJECT SUB RISKS : PACKING : MFAG : EMS : MARINE POLLUTANT : 14.6 ICAO (air transport) CLASS : NOT SUBJECT SUB RISKS : PACKING : PACKING INSTRUCTIONS PASSENGER AIRCRAFT : PACKING INSTRUCTIONS CARGO AIRCRAFT : 14.7 Special precautions in connection with transport : not restricted for any mode of international transport Labelling in accordance with directives 67/548/EEC and 1999/45/EC Contains 2-butanone oxime. May produce an allergic reaction. 14. Transport information SEALANT 559015. Regulatory information The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. N.A. = NOT APPLICABLE N.D. = NOT DETERMINED * = INTERNAL CLASSIFICATION Exposure limits: TLV : Threshold Limit Value - ACGIH US 2000 OES : Occupational Exposure Standards - United Kingdom 1999 MEL : Maximum Exposure Limits - United Kingdom 1999 MAK : Maximale Arbeitsplatzkonzentrationen - Germany 2001 TRK : Technische Richtkonzentrationen - Germany 2001 MAC : Maximale aanvaarde concentratie - the Netherlands 2002 VME : Valeurs limites de Moyenne d’Exposition - France 1999 VLE : Valeurs limites d’Exposition à court terme - France 1999 GWBB : Grenswaarde beroepsmatige blootstelling - Belgium 1998 GWK : Grenswaarde kortstondige blootstelling - Belgium 1998 EC : Indicative occupational exposure limit values - directive 2000/39/EC Full text of any R-phrases referred to under heading 2: R21 : Harmful in contact with skin R36/38 : Irritating to eyes and skin R38 : Irritant to the skin R40 : Limited evidence of a carcinogenic effect R41 : Risk of serious damage to eyes R43 : May cause sensitization by skin contact R48/22 : Harmful: danger of serious damage to health by prolonged exposure if swallowed R53 : May cause long-term adverse effects in the aquatic environment SEALANT 559016. 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