Cation Resin
Cation resin is a negatively charged matrix with exchangeable positive ions (cations). Negatively charged ions are fixed and permanently attached – part of the resin structure. Because the bead is negatively charged only positive ions are attracted or exchanged. For water treatment purposes cation resin can be purchased in the sodium (Na) or hydrogen (H) forms. Always confirm the resin is in the sodium (Na) form before loading the tank and installing in a home. If hydrogen (H) form is used in a residence the pH of the treated water will be very acidic at 2-3 pH. This is damaging to people and pipes. Hydrogen form cation is required commercially when deionizing or demineralizing water.
- The color of the resin has no impact on performance.
- Black cation is available at a premium.
- Cation resin is available as 6%, 8% & 10% crosslink. Higher crosslinked 12-15% cation resins are manufactured for special applications. The higher the crosslink, the higher the cost. A great article by ion exchange expert, Chubb Michaud, gets into the details of crosslinking. http://wcponline.com/2011/06/07/role-cross-linking-ion-exchange-resins/
- Chubb’s highlights:
- Higher cross-linking means higher density with more plastic and less water.
- Higher cross-linking produces a tougher matrix that is more resistant to both chemical oxidation and physical breakdown.
- Drawbacks include higher costs and slower kinetics (not a good thing for cold water). Although higher cross-linked resins have a higher total capacity, the kinetics in colder water may actually result in a lower operating capacity than a lower cross-linked resin and prove to be an incorrect choice.
- Chubb’s highlights:
- How long does resin last?
- In non-chlorinated water 6% resin lasts ~ 8 to 10 years; 8% much longer. In general, the resin will wear out in the same time frame as the other parts of the softener – the valve, tank, brine tank, etc.
- For iron removal applications we recommend using a phosphoric acid drip to keep the resin bed clean so it lasts longer.
- Precautions
- Use sodium form cation not hydrogen form.
- Don’t store outside if there is the possibility of repeated freezing and thawing.
- Don’t overfeed chlorine. Consider an activated carbon filter as pre-treatment.
Urbans Aqua stocks Purolite & Thermax cation resin for quick shipment.
Our rules of thumb when applying these resins:
- 6% – Residential use on well water without chlorine.
- 8% – Residential or Commercial/Industrial well on city water where 1 ppm or less of chlorine.
- 10% – Residential or Commercial/Industrial well on city water where chlorine/chloramine levels are greater than 1 ppm. Also used where there is a combination of hot water and oxidants- chlorine or chloramine).
Installation of an activated carbon filter ahead of the softener to remove the chlorine or chloramine will prolong the life of the resin.
Sodium (Na+) strong base cation resin is commonly used for household, commercial and industrial water softening applications. According to the Water Quality Association, water hardness in the United States ranges from 1 to 350 grains (gpg) per gallon or 17.1 to 5,985 ppm. However, most waters range between 3 and 50 gpg. USGS Water Quality Information
Softening with cation resin is a simple exchange function. The resin bead is negatively charged and attracts positive ions. When supplied in the sodium form (Na+) the resin will exchange sodium ions for hardness ions – calcium and magnesium. The bead is more strongly attracted to these ions and readily exchanges with the sodium. Once the resin is exhausted it is regenerated with a brine solution (NaCl). The brine overwhelms and releases the calcium and magnesium from the bead. The resin is converted back to the sodium form and ready for re-use.
- Free chlorine levels above 0.5ppm or any oxidant decrosslink and shorten cation resin life. Dow Resins Recommended maximum free chlorine levels
- In applications with high chlorine levels and temperature use a 10% crosslinked gel or macroporous resin.
Urbans Aqua stocks:
- Purolite C-100Na C100 Cation Resin Product Data Sheet
- Purolite SSTC6000E
- Purolite C-100EFM Purolite C100EFM
- Thermax Tulsion T42Na Resin Cation TULSION T-42 Na N & Tulsion T52Na Resin Cation TULSION T-52 Na N
- These cation resins are suitable for residential, commercial and industrial applications.
