Avantor, Inc.

HichromChiral Columns

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Hichrom manufactures two ranges of ‘Pirkle-type’ columns for the analysis of a wide range of enantiomers of pharmaceutical or agrochemical origin. CHIRA-chrom 1 type columns contain a stationary phase in which the hydroxyl groups on the silica surface have been modified by a nitrobenzoyl derivative of an optically active amino acid. In the CHIRA-chrom 2 type columns a chiral dinitrophenyltartramide moiety is bonded to the silica surface through a propyl spacer group.

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  • Chiral ‘Pirkle-type’
  • Unique covalent bonding
  • Enantiomer elution order inversion
  • Competitively priced
  • Hichrom high efficiency

Inversion of enantiomer elution order
By substituting L-phenylglycine for D-phenylglycine, the order of elution of the chiral peaks can be reversed. Such a procedure can be useful in assigning peak identity or ensuring prior elution of the minor enantiomer, thus allowing its more accurate determination. The availability of the DL-phenylglycine further aids peak assignment by removing chiral separations whilst maintaining background peak retention profile.