Ionitech Ltd.

IonitechCold-Wall Plasma Nitriding and Nitrocarburising Equipment

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Ionitech's Cold-Wall plasma nitriding and low temperature nitrocarburising equipment are designed for treating parts using pulsed plasma in a vacuum chamber. This type of equipment is particularly suitable for similar shape and size batches. The primary benefits include reduced equipment costs, easy maintenance, and lower electrical energy consumption. The vacuum chambers can be door-type, bell-type, pit-type, or combined-type, all featuring double walls with circulating cooling water to minimize heat exchange. The inner surface incorporates two stainless steel shields separated by thermo-insulating wadding. Parts can be loaded on a metal plate or attached to hanging devices, connected to the cathode of the plasma generator. The process, visible through a sight glass, uses a mixture of hydrogen and nitrogen, with propane or natural gas for nitrocarburising. Cooling is accelerated with argon, and electro-pneumatic valves operate via pressed air. A PC control panel facilitates full process control. The plasma generator consists of multiple components including a power transformer and thyristor rectifier, housed in a metal cabinet cooled by air conditioning. The gas vacuum system includes various valves, mass flow controllers, and pressure gauges, ensuring efficient evacuation and gas filling of chambers.
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The heating of the parts, in a Cold-Wall plasma nitriding installation, is carried out only by pulsed plasma created in the vacuum chamber. This type of plasma nitriding equipment is especially suitable for nitriding similar in shape and size batches of parts. The main advantages of this type of equipment are:

  • Lower cost of the equipment
  • Easy maintenance
  • Lower consumption of electrical energy

The Cold-Wall vacuum chambers’ type could be:

  • Door-type chambers
  • Bell-type chambers
  • Pit-type chambers
  • Combined chambers loaded from the bottom and from the top

The vacuum chambers have double walls, with cooling water circulating in between. In order to decrease the heat exchange between the treated parts and the chamber walls. Two stainless steel shields, separated by thermo-insulating wadding, are installed on the inside surface of the walls and the bottom.

In the door-type chambers and bell-type chambers, the parts are loaded on a metal plate. In the pit-type chambers the parts are attached to special devices to hang. And for the combined-type chambers, the parts could be loaded on a working plate or attached to devices to hang.  The metal plate and the special devices for attachment lie on support insulators and are connected to the cathode of the plasma generator. The process of plasma nitriding could be viewed through a sight glass. The temperature during the process is measured directly in the parts using one or two thermocouples K-type.

The plasma generator and its defense mechanism - a power transformer, a three phase thyristor rectifier, a power choke, a power IGBT switch and a number of circuit breakers, filters and contactors, assembled for different supply voltages and mains frequencies. They are mounted in metal cabinet IP 54 that is cooled with an air conditioning.

The gas vacuum system evacuates the chambers and fills them with treatment gases. It includes a vacuum pump, electro-pneumatic and electromagnetic valves, reducing valves with filters and manometers, mass flow controllers, gas mixer, manual valves, two absolute pressure gauges and vacuum connections.

The pressure gauges are mounted on the chambers bodies. The rest of the components are placed in a ventilated metal enclosure IP54. The process is carried out with a mixture of hydrogen and nitrogen. Propane or natural gas are used for nitrocarburising. After the end of the treatment, the chambers can be filled with argon for accelerated cooling. Pressed air is used for the operation of the electro-pneumatic valves.

The control system consists of a PC controller, main system controller and subsystems (transmitters and drivers) that are connected in a communication network. The Panel PC is equiped with a 15” touchscreen display and uses Windows Embedded Standard 7 operating system.
The technological process is completely automatic. All of the main parameters are controlled by the system controller:
  • •    Pressure in the working chamber
  • Temperature of the processed parts
  • Heat rate
  • Ratio and consumption of working gases
  • Process time length
  • Pulsed Plasma Current
  • Frequency of pulses
  • Duty-cycle of pulses
  • Temperature of cooling water
Specifically designed application, called IonView, implements the operator interface of the ion nitriding installation. It has the following capabilities:
  • Visualization of the technological process parameters
  • Review and editing of technological programs, even while the installation is working
  • Archive of the technological processes
  • Remote access to the archive
  • Visualization of the installation alarms
  • Alarm notification through e-mail and sms
  • Possibility to send process data to Ionitech as attached zip-file through email.

Typical feature of plasma nitriding is the active participation of the treated parts in the glow discharge - the parts act as a cathode, while the chamber acts as an anode. There are many advantages of this method over conventional gas nitriding:

Cost effectiveness
  • 3 to 10 times reduced duration of treatment;
  • 50% - 100 % less energy consumption;
  • 50 to 100 times less working gas consumption;
  • Distortion - none or negligible distortions, because ion nitriding is performed at lower temperature and under vacuum;
  • Higher surface, case and core hardness;
  • Excellent wear resistance - the ion nitriding process produces a compound zone which is dense, nonporous, very hard, not brittle, and has a low coefficient of friction;
  • Reproducible results and better control - the technological process of ion nitriding is fully automated and computer controlled. The parts are heated by the ion bombardment on their surface and therefore the parts are heated uniformly;
  • Surface finish - due to minimum deformations no additional mechanical treatments are necessary;
  • Necessity of predepassivation of stainless steel is eliminated;
  • Masking - surfaces which require masking are easily masked with reusable mechanical masking devices or special paint for masking - 100 % effective;
  • Excellent hygiene and working conditions - the process is not toxic and corresponds to all modern requirements for environmental control.

IONITECH Ltd. Furnaces for Plasma (Ion) Nitriding are fully automated. After loading the parts in the working chamber the technological program begins. It allows – vacuuming and change of the working atmosphere, ion bombardment that creates a sputtering effect and final cleansing of the parts, heating and nitriding (nitrocarburizing). There is a possibility for later oxidation, cooling in plasma, in vacuum or faster with nitrogen or argon.

Scavenging: After vacuuming to 0.5 mbar  the chamber is filled up with working gas to a predetermined pressure for a predetermined time in order to remove any, if left, air inside.

Cleansing: This step is used for preheating and additional cleaning of the treated parts. Before loading the parts in the chamber, they must be cleaned of oil, grease, wax, salt, metallic and mechanical scraps, aluminum, brass etc. Usually the cleaning isn’t perfect and there are some dirties left. The purpose of the cleaning step of the process is to remove all these left dirties. During the cleaning, the plasma current is constant, usually 10-20 % of the maximum value, the electric pulses duty factor is 50 % and the pressure is constant - 0.5-0.8 mbar. The low current and small duty factor prevent arc development, while the parts are cold and yet dirty. The cleaning step lasts from 5 to 30 minutes.

1 to 14 - heat and treatment steps: Here, depending of the type of steel and the results that must be achieved, are applied the heating rate, speed of heating, pressure, duty factor, the working gases and the delay time at a predetermined temperature. During these steps, the parts are heated to reach the nitriding temperature. The current is determined by the temperature regulator. The duty factor is increased from step to step, to become 80 to 95 %. The pressure is increased as well, being constant throughout the step, or going up in conjunction with the temperature.

After the appropriate temperature is reached, the treatment step begins. The temperature, duty factor and pressure stay constant, being respectively 400 - 600 ?C, 80-95 %  and 2.0 - 8.0 mbar. The Plasma (Ion) Nitriding  is carried out with ammonia or with a mixture of hydrogen and nitrogen. When working with hydrogen and nitrogen, the gas ratio can vary from 1:1 to 10:1.
When Plasma (Ion) Nitrocarburizing is carried out - carbon-containing gas is added. It can be methane, propane or natural gas. Its content is from 2 to 10 % of the gas mixture.

The treatment step lasts from several minutes to 20 hours, depending on the parts type and material, and the layer depth technological demands.
The frequency of the electric pulses is constant throughout all the steps. Normally, it is 10 kHz.

The technological process is totally automated. The parameters control, temperature and pressure curves, duty factor changes and gas composition variations are executed by the main controller. If it detects a failure - short circuit in the chamber, high temperature of the chamber walls, gas exhaustion etc.- the controller will stop the process and turn on alarm signals.

Oxidation: In order of achieving better corrosion resistance, our installations allow post-process oxidation.

Cooling: After the end of the Plasma Nitriding process, begins the last part – cooling. In order to prevent unwanted oxidation of the nitrided parts, the cooling could be carried out in plasma, in vacuum neutral gas atmosphere. To decrease the time of cooling - the chamber could be filled with nitrogen or argon.