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Thermal Remediation
The second purpose involves heating the subsurface environment to thermally catalyze sodium persulfate. A total organic carbon (TOC) test is completed with sodium persulfate at 60 C for the oxidant. By thermally activating the persulfate, we can complete an in situ TOC test and destroy a wide range of organic compounds in place.
It is a common misconception that thermal technologies are extremely expensive. For illustrative purposes, the fuel cost to heat one ton of soil by 10C is provided below.
Ø One ton of saturated soil, 30% total porosity requires approximately 15,000 BTUs to raise 10C
Ø One gallon of diesel contains approximately 135,000 BTU
Ø Fuel costs are less than $1 per ton for thermal activation
As a rule-of-thumb estimate, the total cost to heat soil 10C is roughly $5 to $10 per ton, depending upon such factors as soil type, depth, availability of water, etc. The cost of each additional 10C increase is roughly $2 to $3 per ton. A spreadsheet is provided below which allows one to estimate the heat required to heat soil and water in situ. Also, a list of sites where steam activated persulfate has been applied is provideds
