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Adsorbable organic fluorine (AOF) – a sum parameter for non-targeted screening of per- and polyfluorinated alkyl substances (PFASs) in waters
The prevalence of per- and polyfluorinated alkyl substances (PFASs) and other perfluorinated compounds (PFCs) that persist and accumulate in the environment (as well as in our own bodies) is becoming an increasing concern to international health authorities. These chemicals are a class of stable compounds known as «forever chemicals» and are comprised of nearly 10,000 different substances. They are a challenge to monitor indi- vidually and quantify in low concentrations, even in drinking water. Expensive analytical instrumen- tation and experience is required to determine a small selection of individual PFASs, and such anal- yses can be time-consuming and difficult to validate.
A large fraction of synthetic organofluorine substances is assumed to be covered by the sum of all adsorbable fluorine in waters (AOF). Measuring AOF is simpler and faster than targeted analysis methods, and also more sensitive than total fluorine (TF) determination (comprising all organic and inor- ganic F). Measurement of AOF in water samples as an initial screening step gives a fast overview of the actual amount of organic fluorinated compounds present. This can be followed by targeted analyses of individual PFASs if indicated by higher AOF concentrations.
