CDG Solution 3000 - Safety Data Sheet

SDS # CD-004 CDG Solution 3000 Page 1 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week Emergency Telephone Number: 800-424-9300 24 hours/day, 7 days/week CDG Solution 3000TM Safety Data Sheet Product Identifier: Chlorine Dioxide 0.3% Aqueous Solution SDS No. CD-004 Other Means of Identification: Chlorine Oxide Solution Chlorine Peroxide Solution Chlorine (IV) Oxide Solution Chloroperoxyl Solution Recommended Use: Biocide Company: CDG Environmental, LLC 301 Broadway, Suite 420 Bethlehem, PA 18015 888-610-2562 484-821-0780 Emergency Phone Number: 800-424-9300 Section 1 – Chemical Product and Company Identification SDS # CD-004 CDG Solution 3000 Page 2 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week GHS Classification: Skin Irritation: Category 2 Eye Irritation: Category 2B Acute Toxicity – Oral: Category 4 Acute Toxicity – Dermal: Category 4 Acute Toxicity – Inhalation: Category 4 Signal Word: Warning Pictogram: Hazard Statements: Causes skin irritation Causes eye irritation Harmful if swallowed Harmful in contact with skin Harmful in inhaled Precautionary Wash exposed areas thoroughly after handling. Statements: Wear protective gloves and protective clothing. Do not eat, drink or smoke when using this product. Avoid breathing fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. If swallowed: Call a doctor if you feel unwell. Rinse mouth. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a doctor if you feel unwell. Specific treatment (see First Aid Measures on this SDS). Take off contaminated clothing and wash it before reuse. Dispose of contents and container in accordance with local, regional, national and international regulations. Unclassified Hazards: None Ingredients With None Unknown Toxicity: Section 2 – Hazards Identification SDS # CD-004 CDG Solution 3000 Page 3 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week Hazardous component(s): Chemical name Chlorine Dioxide CAS # 10049-04-4 Molecular formula ClO2 Concentration 0.3% (3,000 ppm) Non-hazardous component(s): Chemical name Water CAS # 7732-18-5 Molecular formula H2O Concentration > 99.7% (> 997.000 ppm) Eyes If symptoms develop, move patient away from the source of exposure and into fresh air. Flush eyes gently with large amounts of water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention. Skin Concentrated solutions of the material (> 1000 ppm) may be highly irritating, especially on prolonged contact. Remove contaminated clothing immediately. Immediately flush exposed skin with large amounts of water. Wash thoroughly with mild soap. Consult a physician if irritation or burning persists. Contaminated clothing must be laundered before re-use. Lower concentrations (<1000) ppm may cause some irritation with very-prolonged exposure. Swallowing First aid is not normally required when small amounts of the material are ingested. If symptoms develop or if large amounts of material have been ingested, DO NOT induce vomiting. DO NOT give anything by mouth if the patient is unconscious. Drink large quantities of water. Consult a physician immediately. Neutralization and use of activated charcoal are not recommended. Section 3 – Composition/Information on Ingredients Section 4 – First Aid Measures SDS # CD-004 CDG Solution 3000 Page 4 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Monitor the patient closely for delayed development of pulmonary edema, which may occur up to 72 hours after inhalation. Most Important Symptoms, Acute and Delayed Causes skin and eye irritation. Harmful if swallowed, in contact with skin, or inhaled. Immediate Medical Attention Needed Call poison control center or doctor immediately for treatment advice. Notes to Physicians Probable mucosal damage may contraindicate the use of gastric lavage. NFPA Rating Health – 1 Flammability – 0 Reactivity – 1 Flash Point Not applicable Auto-ignition Temperature Not applicable Explosive Limit Chlorine dioxide solution is not explosive. Chlorine dioxide gas, which may evolve from chlorine dioxide solution, may spontaneously decompose with a mild energy release at concentrations of 10% in air or greater at standard temperature and pressure (i.e., 76 mm Hg partial pressure). Section 5 – Fire-Fighting Measures SDS # CD-004 CDG Solution 3000 Page 5 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week Chlorine dioxide gas may explode with violent force at concentrations of 30% or greater in air at standard temperature and pressure (i.e., 228 mm Hg partial pressure). Hazardous Products of Combustion May form chlorine, hydrochloric acid gas, oxygen on combustion or decomposition. Fire and Explosion Hazards There are no special fire hazards known to be associated with the material. Extinguishing Media Water Fire Fighting Instructions Wear a self-contained breathing apparatus (SCBA) with a full face piece operated in the “positive pressure demand” setting. Use SCBA in conjunction with appropriate chemically resistant personal protective gear. Refer also to the personal protective equipment section of this MSDS. Personal Precautions, Protective Equipment, and Emergency Procedures If run-off occurs, notify proper authorities of any runoff, as required. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Methods and Materials for Containment and Cleaning Up Large spills: Prevent runoff to sewers, streams, lakes or other bodies of water. Small spills: Absorb liquid on vermiculite, floor absorbent or other absorbent material. Flush area with water. Stop spill at source, dike area around spill to prevent spreading, and pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, vermiculite, floor absorbent, or other absorbent material and shoveled into containers. Flush with water the area from which the bulk of the spill has been removed. Section 6 – Accidental Release Measures SDS # CD-004 CDG Solution 3000 Page 6 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week Handling In order to prevent the evolution of chlorine dioxide gas into the breathing zones of workers, agitation of the material should be minimized, and the material should not be stirred, mixed turbulently, sprayed or splashed. Storage The material should be stored indoors, only in the containers in which it is shipped, or in containers authorized by the manufacturer for such storage. Storage temperatures should be maintained above 50°F and below 110°F. The material should not be stored outside or exposed to direct sunlight or freezing temperatures (32°F or below). The material should not be heated to temperatures in excess of 140°F. At temperatures above 140°F, the gas concentration in the headspace of the container may reach high, energetically unstable concentrations. The OSHA permissible exposure limit (PEL) for ClO2 gas in air is 0.1 ppm (0.3 mg/m3 ) as an 8-hour time weighted average. NIOSH recommended exposure limits (REL) and ACGIH threshold limit values (TLV) are also 0.1 ppm. NIOSH and ACGIH short-term exposure limits (STEL) are 0.3 ppm (0.83 mg/m3) for periods not to exceed 15 minutes. The STEL concentration should not be repeated more than 4 times per day and should be separated by intervals of at least 60 minutes. Exposure Guidelines (vapor) OSHA PEL 0.100 ppm – TWA ACGIH TLV 0.100 ppm – TWA ACGIH TLV 0.300 ppm - STEL Eye Protection Wear splash-proof face and eye protection (PVC is preferred) where chlorine dioxide solution may splash or spray. Safety glasses should be in compliance with OSHA regulations. Skin Protection Section 7 – Handling and Storage Section 8 – Exposure Controls / Personal Protection SDS # CD-004 CDG Solution 3000 Page 7 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week Wear waterproof protective clothing (PVC is preferred) where chlorine dioxide solution may splash or spray. Wear resistant gloves, such as Neoprene, to prevent skin contact, wear impervious clothing and boots. Other protective equipment: eyewash station, emergency shower. Respiratory Protection Exposures in the workplace should be monitored to determine if worker exposure exceeds the facility-specified exposure "action level" or the use of the material produces adverse health effects or symptoms of exposure. Provide adequate ventilation to maintain all work areas at concentrations below 0.1 ppm chlorine dioxide concentration. If the generation of vapors or mists is possible, use local ventilation. Where gas concentration may exceed 0.1 ppm, only a NIOSH/MSHA approved full-face acid gas respirator should be used. Monitoring results must be used to assess the proper level or respiratory protection necessary. Proper engineering and/or administrative controls should be used to reduce worker exposure. The facility's respiratory protection program must meet the requirements established in 29 CFR 1910.134, which includes a program for medical evaluation. A NIOSH/MSHA approved self-contained breathing apparatus, with full face piece, is required for leaks and emergencies where the concentration may exceed 5 ppm. Engineering Controls Provide sufficient mechanical ventilation-- general and/or local exhaust-- to maintain exposure below allowable limits. Appearance and odor: Yellow-green liquid, with sharp, pungent odor Odor threshold of gas: 0.1 ppm pH: 5.0 or lower (depending on age and temperature) Freezing Point: 0o C (32o F) Boiling Point: 100o C (212o F) Flash Point: Not applicable Evaporation Rate: Not established Flammability: Not applicable Flammability Limits: Not established Vapor Pressure: Not established Vapor Density: Not established Liquid Specific Gravity: 1.0 at 0o C Solubility: Complete Partition Coefficient (n-octanol/water): Not applicable Auto-ignition Temperature: Not applicabile Decomposition Temperature: No data Viscosity 0.894 cP (centipoise) at 25 °C Section 9 – Physical and Chemical Properties SDS # CD-004 CDG Solution 3000 Page 8 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week Reactivity Material is not reactive under normal conditions of storage and use. Chemical Stability The material, as solution, is stable in the dark. On exposure to light, the solution may decompose to an aqueous solution of chloride and chlorate ions. In regard to vapor (gas) that may evolve from the material, see “Hazardous Decomposition Products” below. Possibility of Hazardous Reactions Material does not undergo hazardous polymerization. Conditions to Avoid Storage temperatures should be maintained above 50°F and below 110°F. The material should not be heated to temperatures in excess of 140°F. Incompatible Materials Avoid exposure to light. Avoid contact with: metals, reducing agents, strong oxidizing agents, sulfur compounds or sulfur-containing components, carbon monoxide, excessive heat, mercury, organic materials, phosphorus. Hazardous Decomposition Products Gas-phase vapors that evolve from the material may decompose on exposure to light, on contact with incompatible materials (see below), or spontaneously at concentrations above 10% in air at standard temperature and pressure (76mm Hg). On decomposition, material may form: Chlorine, hydrochloric acid gas and oxygen. Chlorine dioxide gas is a mucous membrane and respiratory tract irritant. Primary routes of exposure include ingestion, skin and eye contact and inhalation of vapors which may evolve from the material. Target Organ Effects Section 10 – Stability and Reactivity Section 11 – Toxicological Information SDS # CD-004 CDG Solution 3000 Page 9 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week This material may cause mild eye irritation; it is unlikely to cause serious eye irritation or injury. Digestive Tract This material may cause nausea, vomiting and diarrhea; it is unlikely to cause serious digestive tract injury. Chlorine dioxide given daily in drinking water at 1-100 ppm caused a decrease in blood glutathione, altered the morphology of erythrocytes, and caused osmotic fragility in laboratory animals. Respiratory Tract The fumes from this material may cause respiratory tract irritation, wheezing and difficulty breathing. In extreme cases, it may cause pulmonary damage and death. Developmental/Reproductive Effects Available information is insufficient to assess risk to the fetus from maternal exposure to this material during pregnancy. Chlorine dioxide did not cause birth defects in laboratory animals even at very high exposure levels. Cancer Effects Available information is insufficient to assess cancer risk (i.e., carcinogenicity) associated with exposure to this material. This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration (OSHA) United States Environmental Protection Agency (EPA) or American Conference of Industrial Hygienists (ACGIH). Other Health Effects No data available on other possible health effects No data available. Section 12 – Ecological Information Section 13 – Disposal Considerations SDS # CD-004 CDG Solution 3000 Page 10 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week Disposal of this material should be in accordance with all applicable Federal, State and local rules, regulations and requirements. Transport of this material should be in accordance with all applicable Federal, State and local rules, regulations and requirements, including, without limitation, the rules and regulations of the US Department of Transportation, including all applicable packaging and labeling requirements. DOT Information: Regulated as a hazardous material when shipped by motor vehicle or rail car under UN 1760. Proper shipping name: Corrosive Liquid, N.O.S. Class: Class 8 – Corrosive.1 Packing group: III (must not ship or store in metal containers) Hazard label: CORROSIVE Technical name: 0.3% Chlorine Dioxide Aqueous Solution 1 CDG Solution 3000 is a “corrosive material” (Class 8), solely because it is corrosive to steel and aluminum. It is not highly corrosive to skin. It MUST be packaged and shipped in containers that will not react dangerously with or be degraded by the CDG Solution 3000 (e.g., plastic). US Federal Regulations EPA FIFRA Information This chemical is a pesticide product registered by the Environmental Protection Agency (EPA Registration Number 75757-2) and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: Section 14 – Transport Information Section 15 – Regulatory Information SDS # CD-004 CDG Solution 3000 Page 11 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week CAUTION Causes moderate eye irritation. Avoid contact with eyes, skin, or clothing. Harmful if swallowed, absorbed through the skin, or inhaled. Wash thoroughly with soap and water after handling, and before eating, drinking, chewing gum, using tobacco, or using the toilet. TSCA (Toxic Substances Control Act) Status - United States The intentional ingredients of this material are listed. CERCLA RQ- 40 CFR 302.4(a) None listed SARA 302 Components - 40 CFR 355 Appendix A None SARA Section 311/312 Hazard Class-40 CFR 370.2 Chronic Health (No) Acute Heal th (Yes ) Fire ( No ) Reactive ( No) Sudden Release of Pressure (No) SARA 313 Components - 40 CFR 372.65 Section 313 Components CAS Number Percent (%) Chlorine dioxide 10049-04-4 0.3 OSHA Process Safety Management 29 CFR 1910 PSM Component(s) Condition TQ (lbs) CHLORINE DIOXIDE 1000 EPA Accidental Release Prevention 40 CFR 68 PSM Component(s) Condition TQ (lbs) CHLORINE DIOXIDE Chlorine Oxide (ClO2) 1000 International Regulations Not determined SDS # CD-004 CDG Solution 3000 Page 12 of 12 Emergency Telephone Number: 800-424-9300 24 hours, 7 days/week State and Local Regulations California Proposition 65: None on list NSF: Certified to NSF/ANSI Standard 60 and Non-Food Compounds category codes G-5 and G-7. Maximum use rate for potable water – 670 mg/liter. This product ships as NSF certified product from Allentown, PA Kosher: This product has been evaluated and is Star-K Kosher certified. OMRI: This product is OMRI certified product number 857 under classes Processing Sanitizers and Cleaners, Crop Management Tools and Production Aids, and Livestock Management Tools and Production Aids The information set forth herein is believed to be accurate. However, NO WARRANTY IS GIVEN AS TO THE ACCURACY OF ANY OF THE INFORMATION, WHETHER ORIGINATED BY THE COMPANY OR BY OTHERS. Recipients of this SDS are advised to confirm, in advance of any need, that the information is current, applicable, and suitable to their circumstances. Date of Preparation: May 15, 2015 Section 16 – Other Information GHS Classification: Skin Irritation: Category 2 Eye Irritation: Category 2B Acute Toxicity – Oral: Category 4 Acute Toxicity – Dermal: Category 4 Acute Toxicity – Inhalation: Category 4 Signal Word: Warning Pictogram: Hazard Statements: Causes skin irritation Causes eye irritation Harmful if swallowed Harmful in contact with skin Harmful in inhaled Precautionary Wash exposed areas thoroughly after handling. Statements: Wear protective gloves and protective clothing. Do not eat, drink or smoke when using this product. Avoid breathing fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. If swallowed: Call a doctor if you feel unwell. Rinse mouth. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a doctor if you feel unwell. Specific treatment (see First Aid Measures on this SDS). Take off contaminated clothing and wash it before reuse. Dispose of contents and container in accordance with local, regional, national and international regulations. Hazardous component(s): Non-hazardous component(s): Eyes Skin Swallowing Inhalation Most Important Symptoms, Acute and Delayed Causes skin and eye irritation. Harmful if swallowed, in contact with skin, or inhaled. Immediate Medical Attention Needed Call poison control center or doctor immediately for treatment advice. Notes to Physicians NFPA Rating Auto-ignition Temperature Explosive Limit Hazardous Products of Combustion Fire and Explosion Hazards Extinguishing Media Fire Fighting Instructions Personal Precautions, Protective Equipment, and Emergency Procedures Methods and Materials for Containment and Cleaning Up Handling Storage Exposure Guidelines (vapor) Eye Protection Skin Protection Respiratory Protection Engineering Controls Appearance and odor: Yellow-green liquid, with sharp, pungent odor Odor threshold of gas: 0.1 ppm pH: 5.0 or lower (depending on age and temperature) Freezing Point: 0o C (32o F) Flash Point: Not applicable Evaporation Rate: Not established Flammability: Not applicable Flammability Limits: Not established Vapor Pressure: Not established Vapor Density: Not established Liquid Specific Gravity: 1.0 at 0o C Solubility: Complete Partition Coefficient (n-octanol/water): Not applicable Auto-ignition Temperature: Not applicabile Decomposition Temperature: No data Viscosity 0.894 cP (centipoise) at 25 C Reactivity Material is not reactive under normal conditions of storage and use. Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Storage temperatures should be maintained above 50?F and below 110?F. The material should not be heated to temperatures in excess of 140?F. Incompatible Materials Hazardous Decomposition Products Target Organ Effects Digestive Tract Respiratory Tract Developmental/Reproductive Effects Cancer Effects Other Health Effects US Federal Regulations CERCLA RQ- 40 CFR 302.4(a) SARA 302 Components - 40 CFR 355 Appendix A SARA Section 311/312 Hazard Class-40 CFR 370.2 Chronic Health (No) Acute Health (Yes ) SARA 313 Components - 40 CFR 372.65 State and Local Regulations